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Nothing is truly waterproof AND breathable. If you want waterproof then you need rain gear that goes over top your current gear. There is too much pressure when riding for any semi-permeable membrane to work effectively in clothing.

That being said, Scotchguard in the green can works well if the clothing is clean otherwise wash it really well and use something like Nikwax wash in waterproofing stuff. It works great but make sure you don't use your own washing machine.
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